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Diels-Alder reaction

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Diels-Alder reaction [ˈdiːlzˈɔːldə]
n
(Chemistry) Chem a type of chemical reaction in which one organic compound containing conjugated double bonds adds to another containing an ethylenic bond to form a product containing a ring
[named after Otto Diels (1876-1954) and Kurt Alder (1902-58), German chemists]
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Diels-Alder reactions to attach 1,2-dihydro-4-chloroformylbenzocyclobutene end-capped polymers (12) onto EPDM have been performed in a Brabender batch mixer at high temperatures (250-280 [degrees] C).
Functionalization of ethylene-propylene-diene terpolymer via the ... by Thompson, M.R.; Tzoganakis, C.; Rempel, G.L. / Polymer Engineering and Science
5) that BCI-MX, due to its unique chemical structure, reacts with the dienes/trienes formed along the polymer backbone as a result of reversion via the classical Diels-Alder reaction mechanism to form new thermally stable, long and flexible carbon-carbon crosslinks which compensate for the loss of sulfidic crosslinks occurring during reversion (figure 1).
Optimizing tire compound reversion resistance without sacrificing ... by Helt, W.F. / Rubber World
When Corey first reported a laboratory synthesis of prostaglandins 21 years ago, chemists had no way of controlling the orientation at which these two reactants would approach each other during this step, known as a Diels-Alder reaction.
Building chemicals the new-fashioned way by Amato, I. / Science News
 
 
 
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