2] nanoparticles [19-24], Inspired by thiol-lactam-initiated radical polymerizations
in which lactam forms a deactivating persistent radical, similar to TEMPO [25, 26], Lim coated ZnO, [Fe.
The topics include basic principles of polymer molecular weights, mechanical properties of polymer solids and liquids, free-radical polymerization
, ionic and coordinated polymerizations
, and biopolymers.
Among the topics are porous silica in transition metal polymerization
catalysts, supported magnesium-titanium-based Ziegler catalysts for producing polyethylene, product morphology in olefin polymerization
with polymer-supported metallocene catalysts, copper catalysts for olefin polymerization
, ring-opening metathesis polymerizations
and acyclic diene metathesis polymerizations
with homogeneous ruthenium and molybdenum catalysts and initiators.
The chemistry of 2-oxazolines is involved in the polymer synthesis fields of cationic ring-opening polymerization
(CROP) and enzymatic ring-opening polyaddition (EROPA), although both polymerizations
look to be quite a different class of reaction.
One of his most significant discoveries was the use of cyclodextrin as a "phase transport catalyst" in emulsion polymerizations
Kinetic and mechanistic details of these living polymerizations
have been investigated leading to new discoveries in initiator/coinitiator systems, and in reactivity control necessary for macromolecular engineering.
were completed in borosilicate glass ampoules (capacity ~4 mL).
Most recently miniemulsions have been applied in controlled radical polymerizations
whereby relatively narrow molecular weight polymers are produced.
This study has allowed for further understanding of the factors relating to polymerizations
in ordered systems and for further development of Pluronic[R] LLCs as templating agents.
One way to do this is to develop new ways of performing existing polymerizations
Ficel AZDN (azobisisobutyronitrile), azo-polymerization
initiator, provided for free-radical polymerizations
and unsaturated polyesters.
Controlled and Living Polymerizations
in Water Towards Sustainable Solution Polymerization
: Biodiesel as a Polymerization