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van der Waals force
(redirected from Van der Waals bond)

   Also found in: Medical, Encyclopedia, Wikipedia 0.01 sec.
van der Waals force
n.
A weak attractive force between atoms or nonpolar molecules caused by a temporary change in dipole moment arising from a brief shift of orbital electrons to one side of one atom or molecule, creating a similar shift in adjacent atoms or molecules.

[After Johannes Diderik van der Waals (1837-1923), Dutch physicist.]

van der Waals force
A weak force of attraction between electrically neutral molecules that collide with or pass very close to each other. The van der Waals force is caused by the attraction between electron-rich regions of one molecule and electron-poor regions of another (the attraction between the molecules seen as electric dipoles). The attraction is much weaker than a chemical bond. Van der Waals forces are the intermolecular forces that cause molecules to cohere in liquid and solid states of matter, and are responsible for surface tension and capillary action.


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Two model examples--hexamethylbenzene, a centrosymmetric crystal with both covalent and Van der Waals bonds, and anhydrous alum, a nocentrosymmetric structure typical of ceramics and metals--are chosen as model crystals and used to explain symmetry, point groups, space groups, Bravais lattices, reciprocal lattices, and diffraction maxima.
Since van der Waals bonds are weaker than covalent and hydrogen bonds, the breaking of van der Waals bonds occurs in relatively low stress field.
Each seta's tip branches into even finer hairs that nestle so closely with every surface the gecko touches that intermolecular attractions called van der Waals bonds and capillary forces kick in.
 
 
 
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