In the complex microprophries is very fine grained with
orthoclase, perthite, quartz, biotite, magnetite, epidote as major minerals.
Non-stable fragments are represented by subangular K-feldspar grains (
orthoclase and microcline) with [M.sub.d] 0.20 mm, polysynthetically twinned plagioclase, flakes of muscovite and biotite and subangular to subrounded clasts of lutite.
The analysis showed that the composition of the original ash sample included mainly quartz, lime, anhydrite, calcite and smaller amounts of
orthoclase, periclase, gehlenite, larnite, merwinite, pseudowollastonite, hematite, ettringite, melilite and dolomite (Table 2).
Mineral Mohs Relative Scratch Test Vickers kg/ Hardness [mm.sup.2] Talc 1 Easily Scratched by 2.4 Fingernail Gypsum 2 Scratchable by Fingernail 36 Calcium 3 Easly Scratched by Knife 109 Carbonate Fluorite 4 Scratchable by Knife 189 Apatite 5 Difficult to Scratch 536 with Knife
Orthoclase 6 Scratches with Steel File 795 Quartz 7 Scratches Window Glass 1,120 Topaz 8 Scratches Quartz 1,427 Corundum 9 Scratches Topaz 2,060 Diamond 10 Glass Cutter 10,060
Ince, "Influence of
orthoclase phenocrysts on point load strength of granitic rocks," Engineering Geology, vol.
The diffraction reflections of
orthoclase were found at 2[theta] values of 15.4, 21.0, 25.7, 27.5, and 30.1[degrees] (PDF 00-022-1212), whereas the diffraction reflections of muscovite were found at a 2[theta] value of 18.0[degrees] (PDF 00-0582036).
Qz: quartz; Ap: Apatite; Cpx: clinopyroxene; Pl: plagioclase; Or:
orthoclase; Mag: magnetite; Ilm: ilmetite.
The low concentration of soluble [K.sub.2]O present in the phonolite may be due to the predominance of some constituent minerals such as: microcline (KAI[Si.sub.3][O.sub.8]),
orthoclase (KAI[Si.sub.3][O.sub.8]), andesine [(Na,Ca)[(Si,Al).sub.4][O.sub.8]] and e nepheline [(Na, K) AlSi[O.sub.4]] (Teixeira et al., 2012), where K is retained by covalent bonds in the crystalline network of the mineral, presenting low K release to the soil solution (Martins et al., 2008).
The XRD patterns indicate that the sanidine is mixed with other K.-feldspars, such as microclinc and
orthoclase. The sand sample from the R8 ash layer (west area) also contained calcite.