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enthalpy |
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enthalpy [ˈɛnθəlpɪ ɛnˈθæl-] n (Physics / General Physics) a thermodynamic property of a system equal to the sum of its internal energy and the product of its pressure and volume. Symbol H Also called heat content total heat [from Greek enthalpein to warm in, from en-2 + thalpein to warm]
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The observed enthalpy as obtained by DSC is the mathematical sum of the enthalpies of all individual reactions occurring in the temperature range of measurement. obtaining relaxation data on additional heating rates so the activation enthalpies (fitting constants) can be obtained. Properties of a system, such as phase boundaries and enthalpies are described with one set of functions resulting in a consistent description of phase properties. |
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