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hydroxylate |
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| Hydroxylated PCBs have been shown to exhibit estrogenic activity in ER-CALUX assays and, in some cases, are more potent than the parent PCBs (Layton et al. The chemistry of organosilanes can be quite complex involving hydrolytically initiated self-condensation reactions in solvents (including monomers) that can culminate in polymeric silsesquioxane structures, exchange reactions with hydroxylated or carboxylated monomers to form silyl ethers and esters, as well as the formation of silane derived interfaces by adhesive coupling with siliceous mineral surfaces. Other enzymes then clip most hydroxylated chains down to 10 carbon atoms. |
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