isocyanide

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isocyanide

(ˌaɪsəʊˈsaɪəˌnaɪd)
n
(Elements & Compounds) any salt or ester of isocyanic acid. Also called: carbylamine or isonitrile
References in periodicals archive ?
Konishi, Synthesis of 1-Formyl-1, 2-dihydro-quinoline Derivatives by a Lewis Acid-Catalyzed Cyclization of o-(1-Hydroxy-2-alkenyl) Phenyl Isocyanides, Chem.
a skin or respiratory sensitizer or if it is corrosive or has acute irritant effects * a chemical which causes severe effects after a single, repeated or prolonged exposure * a flammable liquid, vapor or aerosols Many chemicals that are used in spray painting, including 2-part polyurethane paints containing isocyanides and toluene (an ingredient in many oil-based paints), and in powder coating, such as triglycidyl isocyanurate, hydrofluoric acid and chromic acid are known to present significant health risks and should be assessed as high risk.
Among the published improvements is the addition of organic compounds like soluble starch (64) or carboxylates and isocyanides.
1988) Screw sense selective polymerization of achiral isocyanides catalyzed by optically active nickel(II) complexes.
The topics include chiral non-racemic isocyanides, Ugi and Passerine reactions with carboxylic acid surrogates, multiple multi-component reactions with isocyanides, the synthesis of pyrroles and their derivatives from isocyanides, and carbene complexes derived from metal-bound isocyanides.
Afterwards, the nanoparticles were employed to act as catalytic agents for the synthesis of isocoumarin derivatives from 2-formylbenzoic acid, isocyanides, and second order amines (dibenzylamine and isopropyl amine) under solvent-free conditions.
He informed that one of the worst of such accidents occurred in Bhopal, India, in 1984, where leaking methyl isocyanides killed 2,000 people.
In addition to growth inhibition of some microbes, the diterpene isocyanides kalihinene and isokalihinol B (Fig.
The chemistry of the isocyanides began in 1859 when Lieke had prepared allyl isocyanide as the first isocyanide [1].
Related (disilene)palladium complexes with isocyanide ligands 75a, 75b, and 76 are synthesized by the reactions of 70b and 74 with the corresponding isocyanide (eqs [30] and [31]) in high yields.