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Pentene has six isomers: 1-pentene (RON = 90.9 and MON = 77.1 [57]), cis-2-pentene (unknown octane number), trans-2-pentene (RON = 94 and MON = 80 [57]), 2-methyl-1-butene (RON = 100.2 and MON = 81.9 [API]), 2- methyl-2-butene (RON = 97.3 and MON = 84.7 [58]), and 3- methyl-1-butene (unknown octane number) as shown in Figure 4.
2j) 1-pentene, IR (KBr): 3080 (=CH), 1645 (C=C), 910, 990 (OOP =CH), 1H-NMR (CDCl3): 0.91 (3H, t, J=8 Hz, CH3); 1.43 (2H, qt, J=8 Hz, J=7.1 Hz, CH2); 2.02 (2H, td, J=7.1 Hz, J=6.2 Hz, CH2); 4.93 (1H, dd, J=10.2 Hz, J=2.1 Hz, CH); 4.97 (1H, dd, J=16.8 Hz, J=2.1 Hz, CH); 5.81 (1H, tdd, J=16.8 Hz, J=10.2 Hz, J=6.2 Hz, CH); 13CNMR (CDCl3) 13.7, 22.3, 36.1, 114.4, 139.0.
Gases detected include benzene, ethanol, ethylbenzene, heptane, hexane, isoprene, methanol, MEK, MIBK, octane, pentane, 1-pentene, toluene, xylene, butane, ethane, methane, propane, ethylene and propylene, www.flir.com/gas.
The comonomer can be [C.sub.2] to [C.sub.10] alkenes such as ethylene, propylene, 1butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, and 4-methyl-1-pentene.
Equistar Chemicals has obtained a patent for an adhesive composition comprised of (a) 2% to 30% weight of a modified polyolefin comprised of a polymer grafted with carboxylic acids, carboxylic acid anhydrides or derivatives thereof, the polymer being selected from a group consisting of (i) ethylene homopolymers, (ii) copolymers of ethylene with propylene, 1-butene, 4-methyl 1-pentene, 1-hexene, or 1-octene, (iii) propylene homopolymers, (iv) copolymers of propylene with ethylene or C4-C10-olefins, and (v) mixtures of (i)-(iv); (b) 0.02% to 0.3% weight of a polyalphaolefin polymer; and 65% to 98% weight of an olefin polymer base resin.
A new crystalline form has been recently reported (14-24) in the case of copolymers of iPP with high contents of 1-hexene or 1-pentene as comonomers.
The failure of the CV formulas has been attributed to numerical inconsistencies which are revisited in this work not only for CV but also for the Deiters method using the same benchmark of 48 conditions and three cubic EOS proposed by Zhi & Lee (2002), including temperatures and pressures in the ranges 87.8K [less than or equal to] T [less than or equal to] 266.3K and 3.56 x [10.sup.-7] Pa [less than or equal to] P [less than or equal to] 1.14 x [10.sup.5] Pa for propylene, 1-butene, and 1-pentene. For each PT, condition results were obtained with the PR, CCOR, and PT cubic EOS using x = Z, x = [??], and x = [??] as variables in Eq.
gas) 34 Pentadecane 9 cis-2-Butene 35 1-Hexadecene 10 1-Pentene 36 Hexadecane 11 Pentane 37 1-Heptadecene 12 cis-2- Pentene 38 Heptadecane 13 1-Hexene 39 1-Octadecene 14 Hexane 40 Octadecane 15 cis-2- Hexene 41 1-Nonadecene 16 Benzene 42 Nonadecane 17 1-Heptene 43 1-Eicosene 18 Heptane 44 Eicosane 19 Toluene 45 1-Heneicosene 20 1-Octene 46 Heneicosane 21 Octane 47 1-Docosene 22 Xylene 48 Docosane 23 1-Nonene 49 1-Tricosene 24 Nonane 50 Tricosane 25 1-Decene 51 1-Tetracosene 26 Decane 52 Tetracosane Table 2.