Diels-Alder reaction


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Diels-Alder reaction

(ˈdiːlzˈɔːldə)
n
(Chemistry) chem a type of chemical reaction in which one organic compound containing conjugated double bonds adds to another containing an ethylenic bond to form a product containing a ring
[C20: named after Otto Diels (1876–1954) and Kurt Alder (1902–58), German chemists]
References in periodicals archive ?
Retro Diels-Alder reaction produced peak at 45 m/z owing to HC=N=O cleavage while peaks at 28 and 63 m/z were due to the loss of N2 and urea molecule respectively.
The Diels-Alder reaction (DA) has a well-known secondary orbital interaction between the diene and the dienophile, which can influence the reaction [14].
Hahn, "Multiple healing effect of thermally activated self-healing composites based on Diels-Alder reaction," Composites Science and Technology, vol.
Sparks, "Type 2 intramolecular N-acylnitroso Diels-Alder reaction: stereoselective synthesis of bridged bicyclic oxazinolactams," Organic Letters, vol.
The reaction has taken place via Ene reaction and Diels-Alder reaction according to Figure 5.
The team looked at a lab-grown ribozyme that catalyzes the Diels-Alder reaction, which has broad applications in organic chemistry.
The research team looked at a lab-grown ribozyme that catalyzes the Diels-Alder reaction, which has broad applications in organic chemistry.
The signature of reversion, conjugated unsaturation in the backbone, serves as the reaction site for crosslink repair via the Diels-Alder reaction using the dienophile 1,3 bis(citraconimidomethyl) benzene (BCI-MX, Perkalink 900) (ref.
Exclusively, our interest is exploring a Diels-Alder reaction of furan and maleic anhydride in water.
The synthesis begins with a Diels-Alder reaction between heterodiene 10 and vinyl ether 3 as the dienophile (Equation 2).