Diels-Alder reaction


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Diels-Alder reaction

(ˈdiːlzˈɔːldə)
n
(Chemistry) chem a type of chemical reaction in which one organic compound containing conjugated double bonds adds to another containing an ethylenic bond to form a product containing a ring
[C20: named after Otto Diels (1876–1954) and Kurt Alder (1902–58), German chemists]
References in periodicals archive ?
It has been widely used in many organic synthesis reactions such as allylation,[15] imino Diels-Alder reaction,[16] reduction[17] and oxidation.
The level of selectivity conferred by the proposed inverse-electron-demand Diels-Alder reaction is key in enabling its use in cells.
22,23) The conversions for Diels-Alder reaction were higher for tung oil compared to conjugated soybean oil.
Kouznetsov VV (2009) Recent Synthetic Developments in a Powerful Imino Diels-Alder Reaction (Povarov Reaction): Application to the Synthesis of N-polyheterocycles and Related Alkaloids.
X-ray crystallographic analysis of 2,5-bis(diphenylmethylsilyl) thiophene monoxides and the Diels-Alder reaction of thiophene monoxide with dienophiles.
The team looked at a lab-grown ribozyme that catalyzes the Diels-Alder reaction, which has broad applications in organic chemistry.
The research team looked at a lab-grown ribozyme that catalyzes the Diels-Alder reaction, which has broad applications in organic chemistry.
The signature of reversion, conjugated unsaturation in the backbone, serves as the reaction site for crosslink repair via the Diels-Alder reaction using the dienophile 1,3 bis(citraconimidomethyl) benzene (BCI-MX, Perkalink 900) (ref.
Exclusively, our interest is exploring a Diels-Alder reaction of furan and maleic anhydride in water.
The synthesis begins with a Diels-Alder reaction between heterodiene 10 and vinyl ether 3 as the dienophile (Equation 2).
6), which was synthesized by Seebach's group and used successfully as a chiral ligand in Diels-Alder reaction [12], carbonyl-ene reaction [13], 1,3-dipolar cycloaddition [14], and nucleophilic addition to carbonyl group [15].