Fluorous


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Flu´or`ous


a.1.Pertaining to fluor.
References in periodicals archive ?
NaHSO4*H2O/activated charcoal [52], 2-chloro-4,6-dimethoxy-1,3,5-triazine [53], melamine trisulfonic acid [54], thiamine hydrochloride [55], hafnium(IV) bis(perfluoro-octanesulfonyl)imide complex supported on fluorous silica gel [56], ultrasound [57], ultrasound/[bmim]BF4 [58], and ultrasound/nano CeO2 [59] are some of the useful protocols which have been reported for the titled transformation.
Exploring Fluorous Affinity by Liquid Chromatography," Anal.
After introductory chapters, he covers perfluoroalkylation; selected fluorinated structures and reaction types; the chemistry of highly fluorinated olefins; fluorous chemistry; fluorous synthesis and combinatorial chemistry; halofluororcarbons, hydroflurorocarbons, and related compounds; and pharmaceutical and other biomedical applications.
A total of 13 presentations were offered over the three-day conference touching on a range of topics including fluorous adhesive coatings, how nanoparticles work to resist corrosion in coatings, and why copper antifouling is still considered a viable product.
Examples of specific topics include nitrogen-containing organofluorine compounds through metathesis reactions, highly diastereoselective anodic fluorination, functional compounds based on hypervalent sulfur fluorides, synthesis of macrolactam marine natural products using fluorous protecting groups, solvent-peptide interaction in fluoroalcohol-water mixtures, and synthesis and conformational analysis of fluorine-containing oligopeptides.
Companion 4x uses precision-packed RediSep normal-phase, reversed-phase, alumina, and fluorous columns.
The lecture presented was titled 'An Introduction to Fluorous Techniques in Organic Synthesis.
Lim, Dispersion polymerization of methyl methacrylate in supercritical CO2 in the presence of non- fluorous random copolymers, Eur.
Among them are the Negishi cross-coupling, metal-catalyzed carbon-heteroatom cross-coupling reactions, enantioselective organocatalysis, asymmetric phase-transfer catalysis, the fluorous linker-facilitated synthesis of biologically interesting molecules, synthetic approaches to bioactive carbohydrates, the precursor-directed biosynthesis of polyketide and non-ribosomal peptide natural products, and DNA as a tool for molecular discovery.