organotin

(redirected from Stannanes)
Also found in: Medical.
Related to Stannanes: Organotin compounds

organotin

(ˌɔːɡænəʊˈtɪn)
adj
(Elements & Compounds) of, concerned with, or being an organic compound with one or more tin atoms in its molecules: used as a pesticide, hitherto considered to decompose safely, now found to be toxic in the food chain
References in periodicals archive ?
Keywords: Batrachotoxin, radical mediated reaction, nBu3SnH, AIBN, alkynyl stannanes.
The formation of alkynyl stannanes (22 and 24) can be exploited in reactions similar to Stille coupling.
The iminium ion doesn't need to be preformed: the addition of benzoyl chloride to the reaction mixture is sufficient to activate a variety of imines toward Pd-catalyzed coupling reactions with vinyl stannanes. Remarkably, even imines containing aryl iodides undergo oxidative addition preferentially at the imine, rather than at the halide (equation 4).