Carotenuto, "Synthesis of polymer-embedded metal, semimetal, or sulfide clusters by thermolysis of
mercaptide molecules dissolved in polymers," Recent Patents on Materials Science, vol.
Relative nucleophilic reactivities of amino groups and
mercaptide ions in addition reactions with [alpha], [beta]-unsaturated compounds.
Moreover, the sulfhydryl group of cysteine moiety of glutathione has a high affinity for metals, forming thermo dynamically stable
mercaptide complexes with several metals, e.g., Cd.
Mercaptide organotin 1 (MOT1) with tin content of 13.9-15.4% and sulfur content of 7.1-8.4% is widely applied in extruded PVC products while
mercaptide organotin 2 (MOT2) consists of 65%-75% bis (2-ethylhexyIthioglycolate) dimethyltin and 25%-35% tris (2-ethylhexylthioglycolate) methyltin.
Thermolite[R] 140 butyltin
mercaptide is specifically designed for coextruded siding, profile, and fence substrates, and more demanding pipe applications where good color-hold and stability are needed.
Name Type Manufacturer Organic calcium KGF-[R.sub.6]H Hangzhou Sanye Auxiliary Co., complex China Organic calcium KGF-[R.sub.6]J Hangzhou Sanye Auxiliary Co., complex China Dibutvltin dilaurate Analytically pure Shanghai Shisihewei Chemical Co., China Mercaptan organotin ZT-237 Beijing Zhenghen Chemical Co., compound China Methyltin
mercaptide TM-181-FS Rohm and Haas Co., USA Preparation of Films
* Thermolite 140 butyltin
mercaptide heat stabilizer is designed for PVC formulations for coextruded siding, profile, and fence substrates, and for pipe applications in which good early color and dynamic stability are important.
To prepare mercaptide-polymer blends, the
mercaptide powder was dissolved or dispersed in chloroform and mixed with a chloroform solution of polystyrene (Aldrich, [M.sub.w] = 230,000 g/mol).
These new grades of alkyl tin
mercaptide stabilizers eliminate the chatter, or vibrations, that occur when an extrusion line is running at high speed.
Available in liquid or solid form, either
mercaptide or sulfur-free, products include butyltins for pipe, siding, window profiles and other applications; as well as octyltin
mercaptide and methyltin
mercaptides for FDA bottles and sheet.