absolute configuration


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absolute configuration

n
(Chemistry) chem the spatial arrangement of atoms or groups in a chemical compound about an asymmetric atom. Also called: absolute stereochemistry See chirality
Translations
configuration absolue
References in periodicals archive ?
The absolute configuration of the C-15 secondary alcohol in 1 was deduced via the CD data of the in situ formed [[Rh.sub.2][(OCOC[F.sub.3]).sub.4]] complex with acetonide 1a (Figure 3).
Provision of a spettropolarimetrico system for the characterization of biomolecules, for the determination of absolute configuration and stereochemical analysis.
(3) In order to study the significance of chirality in pheromonal communications, the first thing to do was to determine the absolute configuration of the naturally occurring pheromone.
"(http://onlinelibrary.wiley.com/doi/10.1002/anie.201208450/full) Absolute Configuration of Beer's Bitter Compounds." Angewandte Chemie International Edition 52: 1553-1555, 28 January 2013.
Kita, "Determination of absolute configuration of trans-2-arylcyclohexanols using remarkable aryl-induced 'H NMR shifts in diastereomeric derivatives," Tetrahedron Letters, vol.
Absolute configuration was determined by circular dichroism spectra (Fig.
5] (d) Absolute configuration was determined by comparison of the specific optical rotation with literature [ref.
VCD is used to determine the absolute configuration of chiral molecules.
In addition, the relationship between absolute configuration and sperm-releasing bioactivily in Laminaria, Alaria, Undaria, and Macrocystis was clarified in bioassays with lamoxirene stereoisomers.
Arnett in pioneering experiments concerning monolayer films of chiral molecules at the air-water interface (Topics in Stereochemistry 13:195-262, 1982), simultaneously writing his doctoral dissertation titled "The Absolute Configuration and Maximum Specifi c Rotation of 1,6-Methano[10]annulene-2-carboxylic Acid."