Electrophilic and nucleophilic additions to acetylide
, vinylidene, vinyl, and carbene ligands," Organometallics, vol.
The reaction is a simply cycloadditon that takes place via copper(I) acetylide
intermediate between ethyl tetrazolo[1,5-a]pyridine-6-carboxylate and respective ethyl propiolate using catalytic amount of copper (I) acetate (Scheme 1) .
Umbarkar, "Selective oxidation of aromatic primary alcohols to aldehydes using molybdenum acetylide
oxo-peroxo complex as catalyst," Tetrahedron Letters, vol.
Roughly 5% of the ring atoms are precipitated as a mixture of silver acetylide
, silver diacetylide, and silver cyanide.
Roberto et al., "A novel diruthenium acetylide
donor complex as an unusual active material for bulk heterojunction solar cells," Organometallics, vol.
Although the mechanistic details are not clear, previous experiments by McNulty and coworkers [9,10] showed that silver acetylide
formation plays an important role in the catalytic cycle as well as other intermediates .
Nishi, "In situ preparation and catalytic activation of copper nanoparticles from acetylide
molecules," Journal of Molecular Catalysis A: Chemical, vol.347, no.
In order to examine the influence of incorporating a transition metal into a |pi~-conjugated system, we have synthesized |8,9~ a number of unsymmetrical bis(acetylide
) complexes of platinum.