PET presents functional groups able to react with reagents such as: water, acid or base (hydrolysis), alcohols as methanol (methanolysis), amines (
ammonolysis) and glycols (glycolysis) [2, 6, 7].
Singh, "Scanning electron microscopic study of hazardous waste flakes of polyethylene terephthalate (PET) by aminolysis and
ammonolysis," Journal of Hazardous Materials, vol.
Ammonolysis of jatrorrhizine (0.05 mol) with ammonia solution (3 mL) -N[H.sub.4]Cl (0.05 mol) in C[H.sub.3]OH at r.t.
The chemical degradation processes of PET waste are frequently demonstrated as follows: hydrolysis (22), (23), glycolysis (24), methanolysis (25), aminolysis (26), (27),
ammonolysis (28), and other processes (29), (30).
Kim, "Morphology and band gap variations ofoxynitride LaTaO[N.sub.2] depending on the
ammonolysis temperature and precursor," Journal of Materials Science, vol.
Apart from the chemical composition, the particle size, crystallinity, and surface area are affected by the
ammonolysis conditions.
Meanwhile,
ammonolysis reaction of DPrC is reversible, so it is economical to obtain slow/ controlled released fertilizer by increasing molar weight of urea.
Also disclosed is a method for producing the acetoacetyl polymer, wherein the method is characterised by comprising the following steps: ammonolysing an acetoacetatc via ester
ammonolysis reaction using an ami no-containing polysiloxane, and/or esterifyinga hydroxyalkyl-containing polysiloxane via transesterification reaction using an acetoacetate.
Many recycling plants have already practiced chemical modification technologies (hydrolysis, methanolysis and
ammonolysis) for polycondensation polymers such as PET and polyurethane; pyrolysis, gasification, catalytic cracking, hydrogenation, coking and visbreaking for polyolefins, PS and PVC [1].