dimethylaniline


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dimethylaniline

(daɪˌmiːθaɪlˈænɪlɪn)
n
a very toxic oily liquid used in industry to harden certain synthetic resins and as a solvent
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The synthetic methodology was triggered by reaction of 2,4- dimethylaniline (1) with benzenesulfonyl chloride (2) at pH 9-10 in aqueous sodium carbonate (10 %) to generate N-(2,4-dimethylphenyl)benzenesulfonamide (3) which was further treated with different aralkylated halides (4a-e) in polar aprotic medium; N, N-dimethylformamide (DMF) and lithium hydride (LiH) which acts as base under stirring at room temperature for 3 hours to afford N- aralkylated-N-(2,4-dimethylphenyl)benzenesulfonamides (5a-e).
dimethylaniline demethylase (DAD) 1.0 ml of modified co-factor solution (prepared by replacing 0.15 MgCl2 with 0.15 M MgCI2/0.1 M semicarbazide) was mixed with 0.5 ml of 20 mM aminopyrine (or benzphetamine or N.N.
In order to investigate these potential properties, four new Schiff base phenoxyimine (PHI) ligands were synthesized from the Schiff base condensation reaction between substituted salicylaldehyde and substituted aniline: 1) ligandl: N-(salicylidene)-3,5-dichloroaniline ([L.sup.1]), 2) ligand2: N-(3,5-dichlorosalicylidene)-3,5 dichloroaniline ([L.sup.2]), 3) ligand 3 N-(3,5-dichlorosalicylidene)- 3,5-bis(trifluoromethyl)aniline ([L.sup.3]), and 4) ligand4: N-(3,5-dichlorosalicylidene)-3,5- dimethylaniline ([L.sup.4]).
Suida and Titsch (1928) acetylated powdered beech and pine using pyridine or dimethylaniline as a catalyst to yield an acetyl weight gain of 30 to 35 percent after 15 to 35 days at 100[degrees]C.
Mixture ratios used for the 8084 resin specimens are 1.50% of the catalyst (MEKP), and 0.30% of the promoters, CoNap-6%, and 0.025% of dimethylaniline by mass of resin.