The 1H-NMR spectrum further displayed signal for methoxyl proton at I' 3.75 (s) and two overlapped doublets due to geminal
protons of another methylene group at I' 3.39 (1H, d, J = 12.4 Hz) and 3.42 (1H, d, J = 12.4 Hz).
tricipital, subescapular, bicipital, supraespinal, abdominal, crural, geminal
) com recurso a um adipometro calibrado (Harpenden, Baty, Inglaterra), sendo o somatorio posteriormente convertido para %MG usando a formula de Withers e colaboradores (1987) (i.e., [%MG=495/(1.0988-0.0004* [SIGMA]7)-450]) recomendada como a mais ajustada para a medicao da %MG em futebolistas (Reilly e colaboradores, 2009).
As mentioned before, the extension with sulfate gives in general rise to a downfield shift of the geminal
and vicinal proton signals.
Although GSH conjugation generally represents a cell-protective process, this reaction sometimes produces cytotoxic, genotoxic, or mutagenic metabolites in the presence of several drugs, such as acetaminophen [3, 4], and industrial chemicals, such as geminal
or vicinal dihaloalkanes [5, 6].
Armstrong, "Using geminal
dicationic ionic liquids as solvents for high-temperature organic reactions," Organic Letters, vol.
Ouyang, "Highly conductive PEDOT:PSS films prepared through a treatment with geminal
diols or amphiphilic fluoro compounds," Organic Electronics: physics, materials, applications, vol.
," an OED word, means "explained as a pair." "Eel-anime," a coined word, is an imaginary musical direction meaning "animatedly, in the manner of eels." "Genialise" with an "s" is found in Chambers)
Hydrogen trioxide--a model compound for studying the conformational modes of geminal
double rotors and five membered rings," J.
** Raparigas: %MG = 0,610 (Prega geminal
+ Prega tricipital) + 5,1;
According to the proposed mechanism, the [sp.sup.3] carbon that supports two geminal
methyls in intermediate (II) is facing one side of the cyclohexene ring, and the aromatic ring is facing other side (Scheme 2).