Several attempts have been made to improve stereoselectivity utilizing chiral isocyanides
and chiral cyclic imines [7-13].
The copper(I) complexes with liquid crystalline properties reported so far are restricted to few classes of ligands related to alkylthiolates , isocyanides
[12-16], phenantroline , azamacrocycles , or Schiff bases derived from 2-iminopyridines [19, 20], giving rise to either mono- or binuclear two- or tetracoordinate complexes.
Konishi, Synthesis of 1-Formyl-1, 2-dihydro-quinoline Derivatives by a Lewis Acid-Catalyzed Cyclization of o-(1-Hydroxy-2-alkenyl) Phenyl Isocyanides
MOF, half-sandwich metal compounds, iridium, isocyanides
* a skin or respiratory sensitizer or if it is corrosive or has acute irritant effects * a chemical which causes severe effects after a single, repeated or prolonged exposure * a flammable liquid, vapor or aerosols Many chemicals that are used in spray painting, including 2-part polyurethane paints containing isocyanides
and toluene (an ingredient in many oil-based paints), and in powder coating, such as triglycidyl isocyanurate, hydrofluoric acid and chromic acid are known to present significant health risks and should be assessed as high risk.
Among the published improvements is the addition of organic compounds like soluble starch (64) or carboxylates and isocyanides
. (70) Adsorption of the organic molecules to the nanoparticle surface limits the growth of the particles and allows for further size control.
(1988) Screw sense selective polymerization of achiral isocyanides
catalyzed by optically active nickel(II) complexes.
Afterwards, the nanoparticles were employed to act as catalytic agents for the synthesis of isocoumarin derivatives from 2-formylbenzoic acid, isocyanides
, and second order amines (dibenzylamine and isopropyl amine) under solvent-free conditions."
He informed that one of the worst of such accidents occurred in Bhopal, India, in 1984, where leaking methyl isocyanides
killed 2,000 people.
In addition to growth inhibition of some microbes, the diterpene isocyanides
kalihinene and isokalihinol B (Fig.
The chemistry of the isocyanides
began in 1859 when Lieke had prepared allyl isocyanide
as the first isocyanide
The use of isocyanides
for the attachment of biologically active substances to polymers.