In this trinuclear
cluster, each terminal metal center shows a tetrahedral ZnN[O.sub.3] coordination geometry from three bridging carboxylate O (Zn2-O3= 1.967[Angstrom], Zn2-O4=1.963[Angstrom] and Zn2-O5= 1.949[Angstrom]) and one N atom of bimib ligand (Zn2-N2=1.986[Angstrom]).
Computational studies also predicted the active site residues histidine and cystine which interact with Cu2+ trinuclear
Mckee, "Mono-, di- and trinuclear
manganese(II) complexes derived from a quinquedentate ligand: Superoxide dismutase and catalase mimetic studies," Inorganica Chimica Acta, vol.
Zhang, "Synthesis, characterization and thermal decomposition of [Sb.sup.III]-M-[Sb.sup.III] type trinuclear
complexes of ethylenediamine-N,N,N',N'-tetraacetate (M: Co(II), La(III), Nd(III), Dy(III))," Journal of Thermal Analysis and Calorimetry, vol.
Mohanty, "Metallo ligands: Part V--Homo and bimetallic trinuclear
complexes of copper(II), nickel(II) and cobalt(II) with 1,8-di-(2'-hydroxyphenyl)-4,5-diphenyl-2,3,6,7-tetrazaoctan-1,3,5,7-tetraene," Indian Journal of Chemistry--Section A Inorganic, Physical, Theoretical and Analytical Chemistry, vol.
He also developed convenient method for the determination of absolute configurations of chiral carboxylic acids, a-amino acids, amino alcohols, polynucleic acids and ephedrine isomers by partially or totally restricting their conformational flexibility through complexation with trinuclear
metals, such as Fe, Cr, Mn, Rh, Ru, etc., L A1/4 water or pyridine and n A1/4 0 or 1.
The difference between type A framework, a trinuclear
system, and type B frameworks, dinuclear system, becomes evident at their secondary building units, visually depicted at Figure S1 in Supplementary Material available online at https://doi.org/10.1155/2017/3237247, along with the subtleness in distinction between compound B1 and compound B2 [26,27].
Pinilla et al., "A trinuclear
Pt(II) compound with short Pt-Pt-Pt contacts.
These types of enzymes will be polymeric and contains generally one of each type 3, type 2 and the type 1 subunit or Centre of copper, wherein the type 3 and type 2 remains close together in forming clusters of trinuclear