The two most commonly occurring mineral forms of CaOx are whewellite
(Ca[C.sub.2][O.sub.4].[H.sub.2]O) and weddellite (Ca[C.sub.2][O.sub.4].2[H.sub.2]O).
Calcium oxalate is found in the majority of kidney stones and exists in the form of CaOx monohydrate (COM, termed as mineral names: whewellite
, Ca[C.sub.2][O.sub.4].[H.sub.2]O), and CaOx dihydrate (COD, weddellite, Ca[C.sub.2][O.sub.4].2[H.sub.2]O), or as a combination of both which accounts for greater than 60% .
The presence of oxalates can suggest a biological attack due to fungal species that can reprecipitate secondary carbonates and biomineralize hyphae with both calcite and whewellite
Tielens et al., "Hyperoxaluria is related to whewellite
and hypercalciuria to weddellite: what happens when crystalline conversion occurs?," Comptes Rendus Chimie, vol.
(3) Calcium oxalate monohydrate (whewellite
), cystine, or calcium phosphate (brushite) stones.
The frequency of the minerals identified was: fifteen samples of whewellite
Ca[C.sub.2][O.sub.4].[H.sub.2]O; eleven huntite samples, nine of which also contained calcite CaC[O.sub.3]; five dolomite samples MgCa[(C[O.sub.3]).sub.2]; two samples of the dihydrate of calcium oxalate, weddellite, Ca[C.sub.2][O.sub.4].2[H.sub.2]O, which came from the walls and ceiling of a rock shelter in the Mitchell Plateau; and there were only single samples of antigorite [Mg.sub.3][Si.sub.2][O.sub.5][(OH).sub.4], a serpentine mineral, and the clay illite (K,[H.sub.30])[Al.sub.2][Si.sub.3]Al[O.sub.10][(OH).sub.2].
Urinary stones maybe composed of calcium oxalate monohydrate (COM, whewellite
), calcium oxalate dihydrate (COD, weddellite), carbonate apatite (CA, dahllite), ammonium urate, magnesium ammonium phosphate (PAM, Struvite), calcium hydrogen phosphate dihydrate (brushite), uric acid (AU0 anhydrous form and AU2 dihydrate form, uricite) and its salts, cystine, xanthine, 2,8-dihydroxyadenine, and drugs .
(5,6) In contrast, the only previous study to have addressed renal stone composition in Iran showed that the most common components were whewellite
(81.5%), weddellite (40.7%), apatite (69%), and ammonium acid urate.
The generalized succession scheme according to Kaspar (1939) is (from oldest to youngest): older carbonates (siderite, ankerite, dolomite), barite, sulphides, whewellite
, nacrite, young carbonates (calcite) and secondary minerals (sulphates).
Upon analysis, the stone was reported as a whewellite
Crystalline calcium oxalates have been found in two different hydration states in plants, either as the monohydrate (whewellite
, Ca[C.sub.2][O.sub.4] x [H.sub.2]O) or as the dihydrate (weddellite, Ca[C.sub.2][O.sub.4] x 2[H.sub.2]O) (Arnott 1982, Monje & Baran 2002b, Franceschi & Nakata 2005, Baran & Monje 2008).